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MDPI AG
Self-Heating Flower-like Nanoconstructs with Limited Incorporation of Yttrium in Maghemite: Effect of Chemical Composition on Heating Efficiency, Cytotoxicity and Genotoxicity
Partial cation substitution can significantly change the physical properties of parent compounds. By controlling the chemical composition and knowing the mutual relationship between composition and physical properties, it is possible to tailor the properties of materials to those that are superior for desired technological application. Using the polyol synthesis procedure, a series of yttrium-substituted iron oxide nanoconstructs, γ-Fe2−xYxO3 (YIONs), was prepared. It was found that Y3+ could substitute...
Download 2023 Željko Žižak , Biljana Dojčinović , Irina Besu Žižak , Tatjana Stanojković , Željko Jaćimović , Bratislav Antić , Dalibor M. Stanković , Milica Kosović-Perutović , Miloš Ognjanović
National Library of Serbia
First cobalt complexes with methyl pyruvate semi/thiosemicarbazone - synthesis, physico-chemical and structural characterization
In the reaction of acetone solutions of CoX2?nH2O (X = Cl, Br) with methyl pyruvate semi/thiosemicarbazone (Hmps, Hmpt) the first Co(II) complexes with these ligands, i.e., [Co(Hmps)(H2O)X2] (X = Cl (1), Br (2)), [Co(Hmpt)2][CoCl4]?2H2? (3) and [Co(Hmpt)2]Br2?Me2CO (4) were obtained. Complexes 1 and 2 represent the first examples of metal complexes of Hmps. All the obtained compounds were characterized by elemental analysis, conductometry, magnetic measurements, and IR spectra, and for complexes...
Download 2020 Ljiljana Vojinovic-Jesic , Željko Jaćimović , Vukadin Leovac , Mirjana Radanovic , Vukoslava Miskov-Pajic , Vukosava Zivkovic-Radovanovic , Marko Rodic , Svetlana Belosevic
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